The relative importance of buffering and brine inputs in controlling the abundance of Na and Ca in sedimentary formation waters   总被引：1，自引：0，他引：1  

Stephanie Houston  Craig SmalleyAdam Laycock  Bruce W.D. Yardley 《Marine and Petroleum Geology》2011,28(6):1242-1251

The concentration of Ca in the formation waters of petroleum reservoirs can play a major role in influencing the outcome of a number of processes that are of great significance to the oil industry. For example, formation water Ca concentration affects the risk of carbonate scale formation during production. In order to better understand the concentrations of Ca in formation waters, we have investigated the chemistries of formation waters from a range of onshore and offshore basins worldwide, using published sources, as well as unpublished data held by BP. Although calcium and sodium are the principal cations in almost all formation waters they vary enormously in their relative proportions. We have identified three distinct trends on a plot of X_Ca (Ca/(Na + Ca)) against Cl. Most data lie on a high-Ca trend, here termed Trend 1, and show an increase in X_Ca with salinity. We interpret this as tracking equilibration with Ca and Na-bearing minerals, with the ratio (mol Ca/mol Na²) remaining approximately constant irrespective of salinity for chloride-dominated fluids. At very high salinities, Br-enriched bittern brines that have taken part in dolomitisation lie at the Cl-rich end of this trend. Some brines remain Na-dominated up to very high salinities and define a distinct low-Ca trend, Trend 2. These are associated with dissolution of halite beds and are interpreted to arise when the amount of Na in the pore fluid greatly exceeds the amount of Ca available in minerals. We refer to such brines as mass-limited; the sparsity of Ca in the rock-fluid system constrains X_Ca to a low value. Remarkably few brines lie between these trends. Finally, dilute formation waters show very large variations in X_Ca and may have bicarbonate as the dominant anion. They define a distinct low-Cl trend, Trend 3. We conclude that the behaviour of Na and Ca in most formation waters reflects equilibration with minerals, and concentrations of Ca in solution are sensitive to pH and P_CO2 as well as to chloride concentration. For some brines however, the amount of salts in solution is sufficient to overwhelm the buffering capacity of the wallrocks.  相似文献   

Diurnal Sea surface temperature response to tropical cyclone Dahlia in the Eastern tropical Indian Ocean in 2017 revealed by the Bailong buoy     

《Dynamics of Atmospheres and Oceans》2020

Tropical Cyclone (TC) Dahlia occurred adjacent to over the equatorial southeastern Indian Ocean during the period 26 November – 3 December 2017 and was observed by the Bailong buoy, which provides in situ observations of high-frequency variations in the upper ocean environment. The diurnal sea surface temperature (dSST) variabilities during different stages of the passage of TC Dahlia are studied. The dSST variability is rather weak during the TC passing stage in contrast to the strong ranges before (0.35 °C) and after (0.57 °C) the TC. Before the influence of TC Dahlia, the dSST presented significant regular variability with a peak in the afternoon and minimum value in the morning, which is similar to the even larger range that occurred after TC Dahlia. During the passage of TC Dahlia, dSST decreased dramatically, and a uniform variation was presented due to the absence of strong heat fluxes and stirring and upwelling induced by strong winds. Further analysis through a one-dimensional mixed layer model (Price-Weller-Pinkel, PWP) indicated that the dominant elements responsible for the different dSST variations during distinct stages of TC Dahlia were shortwave radiation and surface wind, which strongly impacted the dSST evolution during TC Dahlia. The asymmetrical wind strength was responsible for the asymmetry of dSST variation.  相似文献   

Structured Sparse Method for Hyperspectral Unmixing     

《ISPRS Journal of Photogrammetry and Remote Sensing》2014

Hyperspectral Unmixing (HU) has received increasing attention in the past decades due to its ability of unveiling information latent in hyperspectral data. Unfortunately, most existing methods fail to take advantage of the spatial information in data. To overcome this limitation, we propose a Structured Sparse regularized Nonnegative Matrix Factorization (SS-NMF) method based on the following two aspects. First, we incorporate a graph Laplacian to encode the manifold structures embedded in the hyperspectral data space. In this way, the highly similar neighboring pixels can be grouped together. Second, the lasso penalty is employed in SS-NMF for the fact that pixels in the same manifold structure are sparsely mixed by a common set of relevant bases. These two factors act as a new structured sparse constraint. With this constraint, our method can learn a compact space, where highly similar pixels are grouped to share correlated sparse representations. Experiments on real hyperspectral data sets with different noise levels demonstrate that our method outperforms the state-of-the-art methods significantly.  相似文献   

Drifter-derived estimates of lateral eddy diffusivity in the World Ocean with emphasis on the Indian Ocean and problems of parameterisation     

《Deep Sea Research Part I: Oceanographic Research Papers》2014

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黄河三角洲高效生态经济区卤水资源开采潜力评价   总被引：1，自引：0，他引：1       下载免费PDF全文

林存菊  姚英强  付娟 《山东国土资源》2014,30(9)

黄河三角洲高效生态经济区卤水资源较为丰富,历经几十年的集中开采后,已出现卤水开采水位下降、卤度及有益离子含量下降等问题,该文在核算研究区卤水资源量的基础上,结合开发利用现状进行了开采潜力评价,以期为当地卤水资源开采规划提供科学依据。  相似文献   

Diagnostic Study of Global Energy Cycle of the GRAPES Global Model in the Mixed Space-Time Domain          下载免费PDF全文

ZHAO Bin  ZHANG Bo 《Acta Meteorologica Sinica》2014,28(4):592-606

Some important diagnostic characteristics for a model’s physical background are reflected in the model’s energy transport, conversion, and cycle. Diagnosing the atmospheric energy cycle is a suitable way towards understanding and improving numerical models. In this study, formulations of the “Mixed Space-Time Domain”energy cycle are calculated and the roles of stationary and transient waves within the atmospheric energy cycle of the Global-Regional Assimilation and Prediction System （GRAPES） model are diagnosed and compared with the NCEP analysis data for July 2011. Contributions of the zonal-mean components of the energy cycle are investigated to explain the performance of numerical models. The results show that the GRAPES model has the capability to reproduce the main features of the global energy cycle as compared with the NCEP analysis. Zonal available potential energy （AZ） is converted into stationary eddy available potential energy （ASE） and transient eddy available potential energy （ATE）, and ASE and ATE have similar values. The nonlinear conversion between the two eddy energy terms is directed from the stationary to the transient. AZ becomes larger with increased forecast lead time, reflecting an enhancement of the meridional temperature gradient, which strengthens the zonal baroclinic processes and makes the conversion from AZ to eddy potential energy larger, especially for CAT （conversion from AZ to ATE）. The zonal kinetic energy （KZ） has a similar value to the sum of the stationary and transient eddy kinetic energy. Barotropic conversions are directed from eddy to zonal kinetic energy. The zonal conversion from AZ to KZ in GRAPES is around 1.5 times larger than in the NCEP analysis. The contributions of zonal energy cycle components show that transient eddy kinetic energy （KTE） is associated with the Southern Hemisphere subtropical jet and the conversion from KZ to KTE reduces in the upper tropopause near 30？S. The nonlinear barotropic conversion between stationary  相似文献   

Methodological Issues in Researching Migration     

《The Professional geographer》2013,65(1):50-59

Population geographers should consider a mixed methods approach to thestudy of migration. This methodological position arises in response to the challenges of contemporary social theory. It is argued that application of structuration theory favours use of a diversity of methods to investigate the recursive relationship between agency and structure. Similarly a realist stance, as advocated by Sayer (1992), leads to a mixing of methods in order to carry out the synthesising tasks expected of geographers. Postmodernism, when interpreted as method, also points the researcher to consider adopting flexible research practices in order to capture the multiplicities of meaning associated with migration and place. These points are illustrated by a case study of migration to and from Hong Kong.  相似文献   

博茨瓦纳马卡迪卡迪盐湖卤水特征及找钾前景分析     

栾永大  李博昀  谭登华  巴文艳 《化工矿产地质》2019,41(2):90-97

马卡迪卡迪盐湖区为一现代干盐湖,盐湖以湖相碎屑沉积为主,在东侧的苏阿干盐湖赋存有高矿化孔隙卤水,通过对盐湖卤水系统的采样分析及综合研究,卤水主要化学组分为Na+和Cl-,其次为CO3^-2、HCO3^-,SO4^-2、K^+,矿化度平均为257.96g/L,卤水水化学类型为碳酸盐型;卤水组分与矿化度呈明显的正相关,表明卤水还未达到饱和阶段;受湖区构造及补给来源的影响,卤水的富集区位于研究区的西北部,同时也是矿化度最高的地区;KCl的含量在0.39%~0.99%之间,平均在0.65%,已超过液体钾盐矿的最低工业品位,分布面积约690km2,具有一定找矿前景。  相似文献   

Evaluation of boron isotopes in halite as an indicator of the salinity of Qarhan paleolake water in the eastern Qaidam Basin,western China   总被引：1，自引：0，他引：1  

Yongsheng Du  Qishun Fan  Donglin Gao  Haicheng Wei  Fashou Shan  Binkai Li  Xiangru Zhang  Qin Yuan  Zhanjie Qin  Qianhui Ren  Xueming Teng 《地学前缘(英文版)》2019,10(1):253-262

In this study, nineteen brine samples from the Qarhan Salt Lake (QSL) in western China were collected and analyzed for boron (B) and chlorine (Cl) concentrations, total dissolved solids (TDS), pH values and stable B isotopic compositions. The B concentrations and δ¹¹B values of brines in the QSL range from 51.6 mg/L to 138.4 mg/L, and from +9.32‰ to +13.08‰, respectively. By comparison of B concentrations and TDS of brines in QSL with evaporation paths of brackish water, we found that B enrichment of brines primarily results from strong evaporation and concentration of Qarhan lake water. Combining with comparisons of B concentrations, TDS, pH values and δ¹¹B values of brines, previously elemental ratios (K/Cl, Mg/Cl, Ca/Cl, B/Cl) and δ¹¹B values of halite from a sediment core (ISL1A), we observe good correlations between B concentrations and TDS, TDS and pH values, pH and δ¹¹B values of brines, which demonstrate that higher B concentrations and more positive δ¹¹B values of halite indicate higher salinity of the Qarhan paleolake water as well as drier paleoclimatic conditions. Based on this interpretation of the δ¹¹B values of halite in core ISL1A, higher salinity of the Qarhan paleolake occurred during two intervals, around 46–34 ka and 26–9 ka, which are almost coincident with the upper and lower halite-dominated salt layers in core ISL1A, drier climate phases documented from the δ¹⁸O record of carbonate in core ISL1A and the paleomoisture record in monsoonal central Asia, and a higher solar insolation at 30°N. These results demonstrate that the δ¹¹B values of halite in the arid Qaidam Basin could be regarded as a new proxy for reconstructing the salinity record of paleolake water as well as paleoclimate conditions.  相似文献   

Effect of saltwater intrusion on groundwater environment in Weihe River downstream,Shandong Province,China     

MENG Yong-hui  WANG Ji-ning  YU De-Jie  ZHANG Li-xia  FENG Zai-min  YAN Tang  ZHOU Yong 《地下水科学与工程》2019,(3):245-252

Based on the geological and hydrogeological conditions along with dynamic changes of groundwater level,this paper analyzes the hydrodynamic characteristics of saltwater intrusion in the study area.According to monitoring data of groundwater quality,the distribution characteristics of macro component are analyzed,and then fuzzy comprehensive evaluation method is adopted to evaluate the impact of saltwater intrusion on groundwater environment.Concerning the influence degree of groundwater environment,the study area is divided into brine area,seriously influenced area,moderately influenced zone,slightly influenced zone and uninfluenced zone.The results can offer references for prevention and control of saltwater intrusion as well as the protection of water resources.  相似文献